Brake problem is a frozen check valve in the booster line. I've had it happen on most of my cars, and have had good luck cleaning it. Pull it off from the booster, and squirt some MAF or Carb cleaner in there, let it sit for a minute and then start the engine, and spray some more through there with the engine running.
"Correct" fix is to replace that booster hose.
As for your misfire. I'd throw a set of NGK Copper plugs at it, their cheap and easy for that engine...