maintenance history is top priority..
timing - did the whole job get done (ie pulleys, tensioner, water pump, etc) or just the belt? and when?
oil changes done on time?
any history of overheating?
headgaskets ever been done? if so, when?
Personally - and this is my thing - any new to me vehicle that I dont have a complete maintenance history automatically gets a full timing service, oil change, radiator flush & fill, new NGK plugs, wires if needed (also NGK) and all other fluids checked/changed as needed right off the bat.
I then check brakes - condition and wear and replace as needed.
Tires are another thing to check.. all the same brand, size, etc.. wear and condition?